Easiest way is to park up in difflock low or high, neutral main box, no handbrake but chocked wheels, jack one wheel up and try to turn it.
If the jacked wheel won't turn (or won't try to turn the other wheels) then centre difflock works ... but brakes must be off and gears in neutral ...
If it turns then difflock isn't working. It's also worth having someone sit in the vehicle and take it out of difflock then turn again and see what happens.