Is that a genuine LR head or aftermarket? I have found the genuines better,suprise surprise.You appear to have the same problem there as the one I just had skimmed,gas blowout at the back of No4.Mine was also an elring gasket,like yours looks to be.
I would be scrubbing that TOTALLY clean with nylon scourer sponges and paraffin and then dry polishing it ,with a very light touch,with a buffing wheel on a drill.THEM you could see if there was any pitting from the fire blowthrough at the back.Then similar clean of the block face,drain water and oil after to flush out any nasties that have dropped down the cavities.A good rule is to never clean the block with anything that would do damage circulating round a running engine,so no wire wool,wire brushes or hard metal scrapers.
Use brake cleaning fluid or similar solvent to clean head and block before assembly,and let it evapourate before.Everything else has been up on here recently,new bolts etc.
Why a 2 hole replacement gasket,by the way?