Well after giving me the run around for a few days I think I've got to the bottom of it.
I swapped out my valve block for a re-furbed one I had on the shelf, and also cleaned up and renewed the o rings on the drier that I observed bubbling with soapy water. So far so good. Inspecting my NRVs on the old valve block, and they looked pretty good to me. I couldn't feel a ridge or anything like that, and the cones were cone shaped.
Anyway, got it all back together, and although better, still wasn't right. Couldn't see any leaks at the drier, or any of the connections at the new valve block. The tank was still loosing pressure down to 100ish psi when left overnight though. I didn't want to drive it round with the compressor playing catch up all the time, so I put the balloon back on and left it to see what happened, which was nothing. After a little bit of swearing I discovered a leak at the tank! I had checked down there before, but I think I was blindsided by the leaking drier, and maybe NRVs that I didn't consider it could be the tank because I have only just renewed all the pipework, and it wasn't leaking when I checked once.
Lesson learnt is always re-check stuff I suppose. The leak calmed down when the pressure dropped, so you have to get some soapy water on the tank union right after switching off the engine at maximum psi or it didn't show so much.
Anyway, I nicked some O rings from the old valve block (that's probably fine!!) and used them on the drier and the tank. I appear air tight again.... I just need some 8mm and 6mm collett o rings to replace the ones I've used, and my old valve block can become my new spare on the shelf!