I'd recommend against splitting the caliper - sole reason that you may make leaks and you probably don't need to split just the clean the cylinders.
However, you may not make leaks and you might need to split to clean properly, so you decide.
For the brake pipe, get a piece of heavy bar and hammer down on the brake pipe union, as if to hammer it into the caliper. Do this all around it, hard enough to hurt it but not to damage the union. This action will help to loosen the rust etc that will hold it in.
Then you need a 7/16" or 11mm flare nut spanner, which is a heavy duty ring spanner with a slot cut out of the end. Tap it round to loosen the nut (which probably will come undone) and then wiggle to free it from the brake pipe - this may take a few minutes of careful wiggle n lube...
I find it is easier/more successful to use a good socket on the bleed nipple on the bench rather than a spanner on the car, but a spanner may do, depending on rust.
It might be worth getting new bleed nipples from britpart seeing as you're overhauling, they're cheap and nice and new again.
Regards the pistons, I just cleaned up my fronts on my 91 and they were quite rusted, but I didn't fancy 40 quid just on pistons at the moment, so I went for new seals alone. Superb braking and no dragging, new pistons may be needed in a year or so, maybe not...
Anyway, that's all I have to say,
hope it helps